000059803 001__ 59803
000059803 005__ 20181203015933.0
000059803 0247_ $$2doi$$a10.1002/hlca.200390269
000059803 022__ $$a0018-019X
000059803 02470 $$2ISI$$a000186446800004
000059803 02470 $$a4507$$2DAR
000059803 037__ $$aARTICLE
000059803 245__ $$aThe synthesis, characterisation, and reactivity of some polydentate phosphinoamine ligands with benzene-1,3-diyl and pyridine-2,6-diyl backbones
000059803 260__ $$c2003
000059803 269__ $$a2003
000059803 336__ $$aJournal Articles
000059803 520__ $$aThe polydentate phosphinoamines 1,3-{(Ph2P)(2)N}(2)C6H4 and 2,6-{(Ph2P)(2)N}(2)C5H3N have been prepared in a single step from the reaction of the amines 1,3-(NH2)(2)C6H4 or 2,6-(NH2)(2)C5H3N with Ph2PCl in presence of Et3N (1:4:4 molar ratio) in CH2Cl2. Reaction of 1,3-{(Ph2P)(2)N}(2)C6H4 or 2,6-{(Ph2P)(2)N}(2)C5H3N with elemental sulfur or selenium in CH2Cl2 affords the corresponding tetrasulfide or tetraselenide, respectively, in good yield. The complexes [1,3-{Mo(CO)(4)(Ph2P)(2)N}(2)(C6H4)] and [2,6-{Mo(CO)(4)(Ph2P)(2)N}(2)(C5H3N)] were prepared from the reaction reaction of these phosphinoamines with [Mo(CO)(4)(nbd)] (nbd = norbornadiene) in toluene, and the structure of the latter complex has been determined by single-crystal X-ray diffraction analysis.
000059803 6531_ $$aphosphorus-nitrogen chemistry
000059803 6531_ $$ametal-carbonyl-complexes
000059803 6531_ $$a(ph2p)(2)nhdppa
000059803 6531_ $$aclusters
000059803 700__ $$aBiricik, N
000059803 700__ $$0240012$$g153598$$aFei, ZF
000059803 700__ $$0240189$$g148592$$aScopelliti, R
000059803 700__ $$aDyson, PJ$$g149418$$0240015
000059803 773__ $$j86$$tHELVETICA CHIMICA ACTA$$k10$$q3281-3287
000059803 909C0 $$xU9$$0252010$$pLCOM
000059803 909CO $$pSB$$particle$$ooai:infoscience.tind.io:59803
000059803 937__ $$aLCOM-ARTICLE-2003-021
000059803 970__ $$aISI:000186446800004/LCOM
000059803 973__ $$rREVIEWED$$sPUBLISHED$$aEPFL
000059803 980__ $$aARTICLE