Mechanistic in situ high-pressure NMR studies of benzene hydrogenation by supramolecular cluster catalysis with [(eta(6)-C6H6)(eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)][BF4]

Laurenczy, G; Faure, M; Vieille-Petit, L; Suss-Fink, G; Ward, TR

doi:10.1002/1615-4169(200212)344:10&lt;1073::AID-ADSC1073&gt;3.0.CO;2-J

Laurenczy, G; Faure, M; Vieille-Petit, L; Suss-Fink, G; Ward, TR

2002

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Résumé

In situ high-pressure NMR spectroscopy of the hydrogenation of benzene to give cyclohexane, catalysed by the cluster cation [(eta(6)-C6H6) (eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)](+) 2, supports a mechanism involving a supramolecular host-guest complex of the substrate molecule in the hydrophobic pocket of the intact cluster molecule.

Détails

Titre Mechanistic in situ high-pressure NMR studies of benzene hydrogenation by supramolecular cluster catalysis with [(eta(6)-C6H6)(eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)][BF4]

Auteur(s) Laurenczy, G ; Faure, M ; Vieille-Petit, L ; Suss-Fink, G ; Ward, TR

Publié dans ADVANCED SYNTHESIS & CATALYSIS

Volume 344

Numéro 10

Pages 1073-1077

Date 2002

ISSN 1615-4150

Mots-clés (libres)

aqueous-solution; complexes; exchange; activation

DOI https://doi.org/10.1002/1615-4169(200212)344:10<1073::AID-ADSC1073>3.0.CO;2-J

Autres identifiant(s) DAR: 3750
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