Reaction of Ru-3(CO)(12) with supermesityldiphosphene: a new type of reaction of a Group 8 transition metal carbonyl with a diphosphene
Freytag, M; Dyson, PJ; Ernst, L; Jones, PG; Schmutzler, R
2002

Abstract

The reaction of (E)-bis(2,4,6-tri-tert-butylphenyl)diphosphene with Ru-3(CO)(12) results in cleavage of the P=P bond with concomitant C-H activation of one of the t-butyl groups to form Ru-3(mu-H)(2)(CO)(8)(mu-P-C6H2-2,4-Bu-t(2)-6-CMe2CH2)(2). The H-atoms have transferred from the ligand to the metal core. (C) 2002 Elsevier Science B.V. All rights reserved.

Details

Title Reaction of Ru-3(CO)(12) with supermesityldiphosphene: a new type of reaction of a Group 8 transition metal carbonyl with a diphosphene
Author(s) Freytag, M ; Dyson, PJ ; Ernst, L ; Jones, PG ; Schmutzler, R
Published in INORGANIC CHEMISTRY COMMUNICATIONS
Volume 5
Issue 10
Pages 808-810
Date 2002
ISSN 1387-7003
Keywords
DOI https://doi.org/10.1016/S1387-7003(02)00573-7
Other identifier(s) View record in Web of Science
DAR: 882
Laboratories LCOM
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCOM - Laboratory of Organometallic and Medicinal Chemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2005-11-09

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