Intramolecular dynamics of [Rh-4(CO)(6)(mu-PPh2)(4)] in solution
Gullo, E; Detti, S; Laurenczy, G; Roulet, R
2002

Abstract

A Rh-103, P-31 and C-13 NMR study of [Rh-4(CO)(6)(mu-PPh2)(4)] in CD2Cl2 indicates that the strongly bonded, bridging, anionic ligand PPh2- takes part in the site exchange of the carbonyl ligands and is actually mobile about the metallic surface of this cluster compound.

Details

Title Intramolecular dynamics of [Rh-4(CO)(6)(mu-PPh2)(4)] in solution
Author(s) Gullo, E ; Detti, S ; Laurenczy, G ; Roulet, R
Published in Journal of the Chemical Society, Dalton Transactions
Issue 24
Pages 4577-4581
Date 2002
Keywords
DOI https://doi.org/10.1039/B208318C
Other identifier(s) DAR: 3487
View record in Web of Science
Laboratories LCOM
LCCO
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCOM - Laboratory of Organometallic and Medicinal Chemistry
Scientific production and competences > SB - School of Basic Sciences > SB Archives > LCCO - Laboratory of Coordination Chemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2005-11-09

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