Intramolecular dynamics of [Rh-4(CO)(6)(mu-PPh2)(4)] in solution

A Rh-103, P-31 and C-13 NMR study of [Rh-4(CO)(6)(mu-PPh2)(4)] in CD2Cl2 indicates that the strongly bonded, bridging, anionic ligand PPh2- takes part in the site exchange of the carbonyl ligands and is actually mobile about the metallic surface of this cluster compound.


Published in:
JOURNAL OF THE CHEMICAL SOCIETY, DALTON TRANSACTIONS, 24, 4577-4581
Year:
2002
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 Record created 2005-11-09, last modified 2018-01-27


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