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  4. Intramolecular dynamics of [Rh-4(CO)(6)(mu-PPh2)(4)] in solution
 
research article

Intramolecular dynamics of [Rh-4(CO)(6)(mu-PPh2)(4)] in solution

Gullo, E
•
Detti, S  
•
Laurenczy, G  
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2002
Dalton Transactions

A Rh-103, P-31 and C-13 NMR study of [Rh-4(CO)(6)(mu-PPh2)(4)] in CD2Cl2 indicates that the strongly bonded, bridging, anionic ligand PPh2- takes part in the site exchange of the carbonyl ligands and is actually mobile about the metallic surface of this cluster compound.

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Type
research article
DOI
10.1039/B208318C
Web of Science ID

WOS:000179731600010

Author(s)
Gullo, E
Detti, S  
Laurenczy, G  
Roulet, R  
Date Issued

2002

Published in
Dalton Transactions
Issue

24

Start page

4577

End page

4581

Subjects

magnetic-resonance

•

crystal-structure

•

clusters

•

carbonyl

•

fluxionality

•

phosphine

•

exchange

•

ligand

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCOM  
LCCO  
Available on Infoscience
November 9, 2005
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/219858
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