Abstract
The reaction of (E,E)-1-benzyloxy-2-methylpenta-1,3-diene with trimethylsilyl enol ethers derived from acetone or acetophenone with sulfur dioxide precomplexed with ytterbium triflate or (CF3SO2)(2)NH generates sulfinate intermediates that can be quenched by a variety of electrophiles to afford the corresponding polyfunctional sulfones in one-pot operations.
Details
Title
One-pot, four-component synthesis of polyfunctional sulfones
Author(s)
Huang, X. G. ; Vogel, P.
Published in
Synthesis
Issue
2
Pages
232-236
Date
2002
ISSN
0039-7881
Keywords
Note
Ecole Polytech Fed Lausanne, Inst Chim Mol & Biol, Lausanne, Switzerland.
Other identifier(s)
DAR: 43
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Laboratories
LGSA
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > SB Archives > LGSA - Laboratory of Glycochemistry and Asymmetric Synthesis
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date
2005-11-09