One-pot, three-component synthesis of open-chain, polyfunctional sulfones
2002
Abstract
Silyl enol ethers of esters, ketones, as well as allylstannane and allylsilanes react with sulfur dioxide activated with t-BuMe2SiOSO2CF3 to give silyl sulfinates that can be reacted in the same pot with a variety of electrophiles generating the corresponding polyfunctional sulfones. The silyl sulfinate intermediates are formed via ene-reactions following probably concerted mechanisms.
Details
Title
One-pot, three-component synthesis of open-chain, polyfunctional sulfones
Author(s)
Bouchez, L. ; Vogel, P.
Published in
Synthesis-Stuttgart
Issue
2
Pages
225-231
Date
2002
ISSN
0039-7881
Keywords
Note
Ecole Polytech Fed Lausanne, Inst Chim Mol & Biol, Lausanne, Switzerland.
Other identifier(s)
DAR: 42
View record in Web of Science
View record in Web of Science
Laboratories
LGSA
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > SB Archives > LGSA - Laboratory of Glycochemistry and Asymmetric Synthesis
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date
2005-11-09