Journal article

Short, stereoselective syntheses of C(1 -> 3)-linked disaccharides

Nucleophilic additions to D-isolevoglucosenone are face selective and generate the corresponding enolates which react with 1,2:3,4-di-O-isopropylidene-alpha-D-galacto-hexodialdo-1,5-pyranose to give aldol adducts. These can be reduced stereoselectively into C(1-->3) glycosides of 1,6-anhydro-D-galacto-pyranose. (C) 1997 Elsevier Science Ltd. All rights reserved.

    Keywords: Sugar ; oligosaccharides


    Univ Lausanne, Chim Sect, BCH, CH-1015 Lausanne, Switzerland.


    • LGSA-ARTICLE-1998-001

    Record created on 2005-11-09, modified on 2017-05-12


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