The simultaneous double Diels-Alder addition of 1,1-bis(3,5-dimethylfur-2-yl)ethane; Toward a new, asymmetric synthesis of long-chain polypropionate fragments and analogues

The double cycloaddition of 1,1-bis(3,5-dimethylfur-2-yl)ethane to diethyl (E,E)-4-oxohepta-2,5-diene-1,7-dioate gave a single bis-adduct, the hydroboration of which with IpcBH(2) allows the creation of optically active polycyclic systems that are potential precursors of long-chain polypropionate fragments. (C) 1996 Published by Elsevier Science Ltd


Published in:
Tetrahedron Letters, 37, 24, 4149-4152
Year:
1996
ISSN:
0040-4039
Keywords:
Note:
Univ lausanne,bch,sect chem,ch-1015 lausanne,switzerland. univ milan,dipartimento chim fis & elettrochim,i-20133 milan,italy.
Laboratories:




 Record created 2005-11-09, last modified 2018-01-27


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