Total asymmetric synthesis of long-chain, branched carbohydrates and of an aza-C-disaccharide
1996
Abstract
Michael addition of (-)-(1S,5R,6R,7S)-6,7-bis(methoxymethoxy)-2,8-dioxabicyclo[3.2.1]-octan- 3-one lithium enolate to (+)-(1R,4S,5S,6S)-5-benzeneselenyl-6-chloro-3-methylidene-7-oxabicyclo[2 .2.1]heptan-2-one gives a single adduct with highstereoselectivity. it was converted into a derivative of beta-D-(1-->3)-C-linked 1,5-dideoxy-1,5-imino-lyxopyranoside of alpha-D-mannofuranurono-6,1-lactone and other long-chain, branched sugars.
Details
Title
Total asymmetric synthesis of long-chain, branched carbohydrates and of an aza-C-disaccharide
Author(s)
Frerot, E. ; Marquis, C. ; Vogel, P.
Published in
Tetrahedron Letters
Volume
37
Issue
12
Pages
2023-2026
Date
1996
ISSN
0040-4039
Keywords
Note
Univ lausanne,chim sect,bch,ch-1015 lausanne,switzerland.
Laboratories
LGSA
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > SB Archives > LGSA - Laboratory of Glycochemistry and Asymmetric Synthesis
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date
2005-11-09