A Total, Asymmetric-Synthesis of 2-Deoxy-L-Fucose from Furan

The Diels-Alder adduct (+)-l of furan to 1-cyanovinyl (1'S)-camphanate was converted to methyl 3,5-O-diacetyl-2,6-dideoxy-beta-L-lyxo-hexofurano-side ((+)-12), a protected form of 2-deoxy-L-fucose, in 8 steps and 16.6% overall yield.


Published in:
Synthetic Communications, 22, 13, 1883-1893
Year:
1992
ISSN:
0039-7911
Keywords:
Note:
Univ lausanne,chim sect,2 rue barre,ch-1005 lausanne,switzerland.
Laboratories:




 Record created 2005-11-09, last modified 2018-03-17


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