Journal article

Reaction of Dodecacarbonyltriruthenium with 7-Oxabicyclo[2.2.1]Hept-5-En-2-Yl Derivatives - Synthesis of (Mu-3-Eta-2-Benzyne)-Nonacarbonyldihydridotriruthenium and Derivatives

The thermal reaction of [Ru3(CO)12] with 7-oxabicyclo[2.2.1]hept-5-en-2-yl derivatives gave the corresponding [Ru3H2(CO)9(7-oxabicyclo[2.2.1]hept-5-yn-2-yl)] clusters; treatment of the complex derived from 7-oxabicyclo[2.2.1]hept-5-en-2-endo-yl benzoate with (CH3)3SiOSO2CF3 gave a mixture of [Ru3H2(CO)9(benzyne)] and [Ru3H2(CO)9(C6H3-OCOC6H5)].


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