000033500 001__ 33500
000033500 005__ 20180501105832.0
000033500 0247_ $$2doi$$a10.5075/epfl-thesis-3029
000033500 02470 $$2urn$$aurn:nbn:ch:bel-epfl-thesis3029-7
000033500 02471 $$2nebis$$a4759805
000033500 037__ $$aTHESIS_LIB
000033500 041__ $$aeng
000033500 088__ $$a3029
000033500 245__ $$aManganese doped ZnS nanoparticles$$bsynthesis, particle sizing and optical properties
000033500 269__ $$a2004
000033500 260__ $$aLausanne$$bEPFL$$c2004
000033500 300__ $$a167
000033500 336__ $$aTheses
000033500 502__ $$aMartha Liley, Alke Petri-Fink, Günter Schmid, Nava Setter, Horst Vogel
000033500 520__ $$aNanostructured materials can be defined as those materials whose structural elements - clusters, crystallites or molecules - have dimensions in the 1-100 nm range. The explosion in both academic and industrial interest over the past 20 years arises from the remarkable variations in fundamental electrical, optical and magnetic properties that occur as one progresses from an "infinitely extended" solid to a particle of material consisting of a countable number of atoms. In this work the attention was laid on the optical properties of Mn2+ doped ZnS nanoparticles with respect to a possible application as bio sensor in medical and biological analytics. A synthesis for this type of particles has been developed and the nanocrystals obtained have been investigated in terms of their composition, particle size and optical properties. The particles synthesized were stabilized with the amino acid L-cysteine and showed the typical ZnS:Mn emission spectrum with its orange emission due to the 4T1 –> 6A1 transition within the d-orbitals of the Mn2+ at 585 nm and its blue emission due to recombination over the ZnS band gap from shallow electron traps at 380 nm. The onset of the absorption was blue shifted from 340 nm (bulk) to 310 nm, indicating a quantum size effect. The particle sizes and particle size distributions were determined with methods such as transmission electron microscopy, photon correlation spectroscopy, analytical ultra centrifugation and field flow fractionation. The particle size has also been calculated from the shift in the band gap with the help of the effective mass approximation. The limits of the applied techniques are discussed and the particle size distribution determined to go from 3-20 nm with a first maximum at about 5 nm and a second maximum at about 17 nm. The particles' luminescence quantum yields have been determined between 1.5-2 %. They could be enhanced by a factor of three by coating the particles with a SiO2 shell. The quantum yields showed a strong dependence on the dispersion concentration and Mn2+ content. These effects have been investigated with quantum yield measurements at different temperatures and Mn2+ contents, and lifetime measurements. The lifetime measurements showed decay times in the ns region for the blue and in the μs-ms region for the orange emission, indicating a florescence mechanism for the ZnS and a phosphorescence mechanism for the Mn2+ radiation.
000033500 700__ $$0(EPFLAUTH)144405$$aAxmann, Yvonne$$g144405
000033500 720_2 $$0240408$$aHofmann, Heinrich$$edir.$$g105410
000033500 8564_ $$s2245207$$uhttps://infoscience.epfl.ch/record/33500/files/EPFL_TH3029.pdf$$yTexte intégral / Full text$$zTexte intégral / Full text
000033500 909C0 $$0252068$$pLTP$$xU10340
000033500 909CO $$ooai:infoscience.tind.io:33500$$pDOI$$pthesis$$pthesis-bn2018$$pDOI2$$pSTI
000033500 918__ $$aSTI$$bSTI-SMX-1$$cIMX
000033500 919__ $$aLTP
000033500 920__ $$a2004-7-13$$b2004
000033500 970__ $$a3029/THESES
000033500 973__ $$aEPFL$$sPUBLISHED
000033500 980__ $$aTHESIS