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  4. Light-Induced Halide Segregation in 2D and Quasi-2D Mixed-Halide Perovskites
 
research article

Light-Induced Halide Segregation in 2D and Quasi-2D Mixed-Halide Perovskites

Datta, Kunal
•
Caiazzo, Alessandro
•
Hope, Michael A.
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March 3, 2023
Acs Energy Letters

Photoinduced halide segregation hinders widespread application of three-dimensional (3D) mixed-halide perovskites. Much less is known about this phenomenon in lower-dimensional systems. Here, we study photoinduced halide segregation in lower-dimensional mixed iodide-bromide perovskites (PEA2MAn-1Pbn(BrxI1-x)3n+1, with PEA+: phenethylammonium and MA+: methylammonium) through time-dependent photoluminescence (PL) spectroscopy. We show that layered two-dimensional (2D) structures render additional stability against the demixing of halide phases under illumination. We ascribe this behavior to reduced halide mobility due to the intrinsic heterogeneity of 2D mixed-halide perovskites, which we demonstrate via 207Pb solid-state NMR. However, the dimensionality of the 2D phase is critical in regulating photostability. By tracking the PL of multidimensional perovskite films under illumination, we find that while halide segregation is largely inhibited in 2D perovskites (n = 1), it is not suppressed in quasi-2D phases (n = 2), which display a behavior intermediate between 2D and 3D and a peculiar absence of halide redistribution in the dark that is only induced at higher temperature for the quasi-2D phase.

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Type
research article
DOI
10.1021/acsenergylett.3c00160
Web of Science ID

WOS:000975364100001

Author(s)
Datta, Kunal
Caiazzo, Alessandro
Hope, Michael A.
Li, Junyu
Mishra, Aditya  
Cordova, Manuel  
Chen, Zehua
Emsley, Lyndon  
Wienk, Martijn M.
Janssen, Rene A. J.
Date Issued

2023-03-03

Publisher

AMER CHEMICAL SOC

Published in
Acs Energy Letters
Subjects

Chemistry, Physical

•

Electrochemistry

•

Energy & Fuels

•

Nanoscience & Nanotechnology

•

Materials Science, Multidisciplinary

•

Chemistry

•

Science & Technology - Other Topics

•

Materials Science

•

suppressed ion migration

•

tandem solar-cells

•

hybrid perovskites

•

phase segregation

•

performance

•

efficiency

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LRM  
Available on Infoscience
May 22, 2023
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/197726
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