Heterogeneous Overhauser-DNP on H-1 dominated by scalar coupling in aqueous solution
2022
Abstract
The Overhauser Dynamic Nuclear Polarization (O-DNP) of H-1 nuclei usually involves a dipolar coupling with the polarizing agent, whereas scalar coupling via hyperfine interactions are more common with C-13 nuclei. Here, we show a scalar-coupling dominated H-1 O-DNP, using polyaniline as a heterogeneous polarizing agent in an aqueous solution.
Details
Title
Heterogeneous Overhauser-DNP on H-1 dominated by scalar coupling in aqueous solution
Author(s)
Milani, Jonas ; Saenz, Felipe ; Roussel, Christophe ; Ansermet, Jean-Philippe
Published in
Magnetic Resonance In Chemistry
Date
2022-11-07
Publisher
Hoboken, WILEY
ISSN
0749-1581
1097-458X
1097-458X
Keywords
Other identifier(s)
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Laboratories
SB-SCGC
Record Appears in
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Work produced at EPFL
Journal Articles
Published
Record creation date
2022-11-21