Nitrogen-doped graphene stabilized copper nanoparticles for Huisgen [3+2] cycloaddition "click" chemistry

Nitrogen-doped reduced graphene oxide (NRGO) stabilized copper nanoparticles are designed to assist Cu(I)-catalyzed Huisgen [3+2] cycloaddition "click" chemistry (CuAAC). This study demonstrates a robust route for the synthesis of vastly dispersed heterogeneous catalysts (NRGO/Cu2O), achieving CuAAC at low temperaturewithout any external additive (oxidizing/reducing agent) with high stability and recyclability. Underlying mechanisms are analysed using DFT calculations, confirming the experimental results.


Published in:
Chemical Communications, 55, 44, 6249-6252
Year:
Jun 04 2019
Publisher:
Cambridge, ROYAL SOC CHEMISTRY
ISSN:
1359-7345
1364-548X
Keywords:
Laboratories:




 Record created 2019-06-18, last modified 2019-07-09


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