Alkene hydrosilylation catalyzed by easily assembled Ni(II)-carboxylate MOFs

We report the first Ni MOF catalysts for anti-Markovnikov hydrosilylation of alkenes. These catalysts are bench-stable and easily-assembled from simple Ni salts and carboxylic acids. The best catalyst gives turnover numbers up to 9500 and is robust even after 10 recycling runs. The catalyst can be applied for the hydrosilylation of a wide range of alkenes, achieving good synthetic utility and functional group tolerance.


Published in:
Chemical Science, 10, 13, 3791-3795
Year:
Apr 07 2019
ISSN:
2041-6520
2041-6539
Keywords:
Laboratories:




 Record created 2019-06-18, last modified 2019-08-19

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