000263953 001__ 263953
000263953 005__ 20190218181325.0
000263953 0247_ $$2doi$$a10.1039/C8CP06666C
000263953 02470 $$a10.1039/C8CP06666C$$2DOI
000263953 037__ $$aARTICLE
000263953 245__ $$aEnergy and orientation independence of the channel branching in Ne* + ND3 chemi-ionisation
000263953 260__ $$c2019-01-15
000263953 269__ $$a2019-01-15
000263953 336__ $$aJournal Articles
000263953 520__ $$aCollisions of excited neon atoms with ammonia molecules can lead to two reaction processes, dissociative ionisation and Penning ionisation. Both processes result in the ionisation of the ammonia molecule and redistribution of the electronic energy into the internal ammonia ion rovibrational modes. We performed energy dependent, crossed-beam stereodynamics studies of the branching ratio between the two ionisation processes. It was found that the branching ratio is totally and completely insensitive to both the neon orientation and the collision energy across the range we sampled, 370–520 cm
000263953 536__ $$aFNS$$c200021_165975
000263953 6531_ $$aCold Chemistry
000263953 6531_ $$aMerged Beams
000263953 6531_ $$aStereodynamics
000263953 6531_ $$aPenning Ionisation
000263953 6531_ $$aAmmonia
000263953 700__ $$aGordon, Sean D. S.
000263953 700__ $$aOsterwalder, Andreas
000263953 773__ $$tPhysical Chemistry Chemical Physics
000263953 8560_ $$fandreas.osterwalder@epfl.ch
000263953 909C0 $$yApproved$$pGR-OST$$xU12027$$mandreas.osterwalder@epfl.ch$$zBorel, Alain$$0252210
000263953 909CO $$ooai:infoscience.epfl.ch:263953$$particle$$pSB
000263953 960__ $$aandreas.osterwalder@epfl.ch
000263953 961__ $$apierre.devaud@epfl.ch
000263953 973__ $$sPUBLISHED$$aEPFL$$rREVIEWED
000263953 980__ $$aARTICLE
000263953 981__ $$aoverwrite