Ketene Aminal Phosphates: Competent Substrates for Enantioselective Pd(0)-Catalyzed C-H Functionalizations
Grosheva, Dania; Cramer, Nicolai
2017
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Abstract

Enantioselective Pd(0)-catalyzed C-H functionalizations of ketene aminal phosphates provide isoindoline scaffolds with high enantioselectivity at ambient temperature. The high level of enantiocontrol is enabled by a tailored monodentate electron-rich phosphine ligand featuring a point chiral phospholane module and a bulky atropchiral binaphthyl backbone.

Details

Title Ketene Aminal Phosphates: Competent Substrates for Enantioselective Pd(0)-Catalyzed C-H Functionalizations
Author(s) Grosheva, Dania ; Cramer, Nicolai
Published in Acs Catalysis
Pagination 4
Volume 7
Issue 11
Pages 7417-7420
Date 2017
ISSN 2155-5435
Keywords
DOI https://doi.org/10.1021/acscatal.7b02783
Other identifier(s) View record in Web of Science
Laboratories LCSA
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCSA - Laboratory of Asymmetric Catalysis and Synthesis
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2017-12-04

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