Leaching from Palladium Nanoparticles in an Ionic Liquid Leads to the Formation of Ionic Monometallic Species

Molecular dynamics simulations and DFT calculations suggest that leaching of palladium species from Pd nanoparticles in ionic liquids does not involve "naked" Pd(0) atoms or neutral ArPdX species formed by oxidative addition of arylhalides. Instead, the ionic liquid contributes largely to leaching of ionic PdX- or PdAr+ species.


Published in:
Journal Of Physical Chemistry Letters, 8, 15, 3452-3456
Year:
2017
Publisher:
Washington, Amer Chemical Soc
ISSN:
1948-7185
Laboratories:




 Record created 2017-09-05, last modified 2018-09-13


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