000227599 001__ 227599
000227599 005__ 20181203024641.0
000227599 0247_ $$2doi$$a10.1002/slct.201601583
000227599 022__ $$a2365-6549
000227599 02470 $$2ISI$$a000395533100028
000227599 037__ $$aARTICLE
000227599 245__ $$aEfficient Electrochemical Production of Peroxodicarbonate Applying DIACHEM (R) Diamond Electrodes
000227599 260__ $$bWiley-V C H Verlag Gmbh$$c2017$$aWeinheim
000227599 269__ $$a2017
000227599 300__ $$a4
000227599 336__ $$aJournal Articles
000227599 520__ $$aThe electrochemical synthesis of peroxodicarbonate was performed on boron-doped DIACHEM((R)) diamond anodes (BDD). The influence of various parameters was studied and promising conditions were determined in an undivided cell design by CONDIAS GmbH. The best performance was obtained with a temperature below room temperature (< 18 degrees C), high current density (720 mA cm(-2)), high flow velocity (170 cm s(-1)) and starting concentration close to the maximum solubility of sodium carbonate (1.5 M Na-carbonate). A high concentration of peroxodicarbonate of 282 mM was obtained with highest current efficiency of about 76%. Future industrial applications appear to be promising. Experiments performed to investigate the bleaching power of the peroxodicarbonate gave promising results. Additionally, a new type of DIACHEM((R)) diamond electrode based on Molybdenum substrate was successfully tested.
000227599 6531_ $$aBleaching
000227599 6531_ $$acarbonate
000227599 6531_ $$adiamond electrodes
000227599 6531_ $$aelectrochemistry
000227599 6531_ $$aperoxodicarbonate
000227599 700__ $$uCONDIAS GmbH, Fraunhoferstr 1b, D-25524 Itzehoe, Germany$$aChardon, Chloe P.
000227599 700__ $$uCONDIAS GmbH, Fraunhoferstr 1b, D-25524 Itzehoe, Germany$$aMatthee, Thorsten
000227599 700__ $$uCONDIAS GmbH, Fraunhoferstr 1b, D-25524 Itzehoe, Germany$$aNeuber, Rieke
000227599 700__ $$uCONDIAS GmbH, Fraunhoferstr 1b, D-25524 Itzehoe, Germany$$aFryda, Matthias
000227599 700__ $$g104807$$aComninellis, Christos$$0240416
000227599 773__ $$j2$$tChemistryselect$$k3$$q1037-1040
000227599 909C0 $$0252005$$pGGEC$$xU10173
000227599 909CO $$particle$$ooai:infoscience.tind.io:227599
000227599 937__ $$aEPFL-ARTICLE-227599
000227599 973__ $$rREVIEWED$$sPUBLISHED$$aEPFL
000227599 980__ $$aARTICLE