000226068 001__ 226068
000226068 005__ 20180317094435.0
000226068 0247_ $$2doi$$a10.1002/anie.200705113
000226068 022__ $$a1433-7851
000226068 037__ $$aARTICLE
000226068 245__ $$aThe versatile chemistry and non-centrosymmetric crystal structures of salt-inclusion vanadate hybrids
000226068 260__ $$c2008
000226068 269__ $$a2008
000226068 336__ $$aJournal Articles
000226068 520__ $$aThree unique structure types of the vanadate-based mixed-metal oxide systems (salt)·MnII-Vv-O and (salt)·CuII-Vv-O are presented, with a focus on the role of the asym. vanadate units. Lattice parameters were obtained for (CsCl)2Mn(VO3)2, (CsBr)2Mn(VO3)2, (RbCl)2Mn(VO3)2, (CsCl)2Cu(VO3)2, (CsCl)Mn2(V2O7), (KCl)2Cu(VO3)2, (RbCl)2Cu(VO3)2 and (CsBr)2Cu(VO3)2. The two structure types found in the (AX)2M-(VO3)2 series differ in the propagation direction of the metavanadate chains which is thought to be due to the presence (or absence) of a Jahn-Teller distortion of the metal (d9 Cu2+ vs. d5 Mn2+) ion.
000226068 6531_ $$abond valence sum manganese copper salt inclusion vanadate compd
000226068 6531_ $$acopper salt inclusion vanadate hybrid compd prepn structure
000226068 6531_ $$acrystal structure manganese copper salt inclusion vanadate hybrid compd
000226068 6531_ $$amanganese salt inclusion vanadate hybrid compd prepn structure
000226068 700__ $$0249115$$aQueen, Wendy L.$$g253110
000226068 700__ $$aWest, J. Palmer
000226068 700__ $$aHwu, Shiou-Jyh
000226068 700__ $$aVanDerveer, Donald G.
000226068 700__ $$aZarzyczny, Matthew C.
000226068 700__ $$aPavlick, Ryan A.
000226068 773__ $$j47$$q3791-3794$$tAngewandte Chemie, International Edition
000226068 909CO $$ooai:infoscience.tind.io:226068$$particle$$pSB
000226068 909C0 $$0252547$$pLFIM$$xU13001
000226068 937__ $$aEPFL-ARTICLE-226068
000226068 970__ $$aqueen_versatile_2008/LFIM
000226068 973__ $$aOTHER$$rREVIEWED$$sPUBLISHED
000226068 980__ $$aARTICLE