The chiral expression of a molecule on a surface is driven from a random solid solution on Cu(100) to a racemic crystal on a Sn/Cu(100) alloy. Density functional theory simulations reveal how the growth of the racemate is influenced by the underlying surface.
Titre
Chiral expression of adsorbed (MP) 5-amino[6] helicenes: from random structures to dense racemic crystals by surface alloying
Publié dans
Chemical Communications
Pagination
4
Volume
53
Numéro
1
Pages
130-133
Date
2017
Editeur
Cambridge, Royal Soc Chemistry
ISSN
1359-7345
Date de création de la notice
2017-02-17