000221940 001__ 221940
000221940 005__ 20190506204153.0
000221940 022__ $$a1359-7345
000221940 02470 $$2ISI$$a000382122200018
000221940 0247_ $$a10.1039/c6cc05730f$$2doi
000221940 037__ $$aARTICLE
000221940 245__ $$aSynthesis of cyclic carbonates from diols and CO2 catalyzed by carbenes
000221940 269__ $$a2016
000221940 260__ $$c2016
000221940 300__ $$a4
000221940 336__ $$aJournal Articles
000221940 520__ $$aThe synthesis of cyclic carbonates from epoxides and CO2 is a well-established reaction, whereas the synthesis of cyclic carbonates from diols and CO2 is considerably more challenging, and few efficient catalysts are available. Here, we describe heterocyclic carbene catalysts, including one derived from a cheap and efficient thiazolium salt, for this latter reaction. The reaction proceeds at atmospheric pressure in the presence of an alkyl halide and Cs2CO3. Reaction mechanisms for the transformations involved are also proposed.
000221940 542__ $$fCC BY
000221940 700__ $$g194257$$aBobbink, Felix D.$$0248167
000221940 700__ $$aGruszka, Weronika
000221940 700__ $$g255221$$aHulla, Martin$$0249314
000221940 700__ $$g229963$$aDas, Shoubhik$$0247009
000221940 700__ $$g149418$$aDyson, Paul J.$$0240015
000221940 773__ $$q10787-10790$$k71$$j52$$tChemical Communications
000221940 8560_ $$fbeatrice.marselli@epfl.ch
000221940 8564_ $$s1736196$$zFinal$$uhttps://infoscience.epfl.ch/record/221940/files/Synthesis%20of%20cyclic%20carbonates%20from%20diols%20and%20CO2%20catalyzed%20by%20carbenes.pdf
000221940 909C0 $$xU9$$0252010$$pLCOM
000221940 909CO $$pSB$$particle$$ooai:infoscience.tind.io:221940
000221940 917Z8 $$x135992
000221940 937__ $$aEPFL-ARTICLE-221940
000221940 973__ $$rREVIEWED$$sPUBLISHED$$aEPFL
000221940 980__ $$aARTICLE