Alkoxy Hydrosilanes As Surrogates of Gaseous Silanes for Hydrosilylation of Alkenes
Busbov, Ivan; Keller, Sebastien Carlos; Hu, Xile
2016
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Abstract

Me2SiH2, MeSiH3, and SiH4 are gaseous and flammable silanes that are inconvenient to use in chemical reactions. Catalytic amounts of a nickel pincer complex and NaO'Bu are reported to allow the synthesis of alkyl hydrosilanes from alkenes and alkoxy hydrosilanes, leading to the replacement of Me2SiH2, MeSiH3, and SiH4 by Me-2(MeO)SiH, Me(EtO)(2)SiH, and (MeO)(3)SiH in hydrosilylation reactions of alkenes. The scope and mechanism of the reactions are also described.

Details

Title Alkoxy Hydrosilanes As Surrogates of Gaseous Silanes for Hydrosilylation of Alkenes
Author(s) Busbov, Ivan ; Keller, Sebastien Carlos ; Hu, Xile
Published in Organic Letters
Pagination 4
Volume 18
Issue 8
Pages 1928-1931
Date 2016
ISSN 1523-7060
DOI https://doi.org/10.1021/acs.orglett.6b00792
Other identifier(s) View record in Web of Science
Laboratories LSCI
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LSCI - Laboratory of Inorganic Synthesis and Catalysis
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2016-07-19

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