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research article
TADDOL-based phosphorus(III)-ligands in enantioselective Pd(0)-catalysed C-H functionalisations
Monodentate TADDOL-derived phosphoramidites and phosphonites are versatile chiral ligands for enantio-selective Pd(0)-catalysed C-H functionalisations. They enable highly selective cyclisations to access a wide range of chiral carbo-and heterocycles. The high attractiveness of this ligand class consists in their modular structure, allowing for a quick assembly of a library with variable steric properties. Asymmetric C-H functionalisation methods utilising catalytic systems based on Pd(0) complexes and TADDOL-type ligands are presented and aspects of selectivity are discussed.
Type
research article
Web of Science ID
WOS:000366664300001
Authors
Publication date
2015
Publisher
Published in
Volume
51
Issue
100
Start page
17647
End page
17657
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
February 16, 2016
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