Enhancement of p-type dye-sensitized solar cell performance by supramolecular assembly of electron donor and acceptor

Supramolecular interactions based on porphyrin and fullerene derivatives were successfully adopted to improve the photovoltaic performance of p-type dye-sensitized solar cells (DSCs). Photoelectron spectroscopy (PES) measurements suggest a change in binding configuration of ZnTCPP after co-sensitization with C60PPy, which could be ascribed to supramolecular interaction between ZnTCPP and C60PPy. The performance of the ZnTCPP/C60PPy-based p-type DSC has been increased by a factor of 4 in comparison with the DSC with the ZnTCPP alone. At 560 nm, the IPCE value of DSCs based on ZnTCPP/C60PPy was a factor of 10 greater than that generated by ZnTCPP-based DSCs. The influence of different electrolytes on charge extraction and electron lifetime was investigated and showed that the enhanced V oc from the Co 2+/3+ (dtbp) 3 -based device is due to the positive E F shift of NiO.


Published in:
Scientific Reports, 4
Year:
2014
ISSN:
20452322
Laboratories:




 Record created 2015-10-19, last modified 2018-03-17


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