Porphyrin Sensitizers Bearing a Pyridine-Type Anchoring Group for Dye-Sensitized Solar Cells

Three novel efficient donor-acceptor porphyrins, MH1-MH3, with a pyridine-type acceptor and anchoring group were synthesized and their optical, electrochemical, and photovoltaic properties investigated. Replacing the commonly used 4-carboxyphenyl anchoring group with 2-carboxypyridine, 2-pyridone, and pyridine did not significantly change the absorption and electrochemical properties of the porphyrin dyes. These new porphyrin dyes MH show power conversion efficiencies of 8.3%, 8.5%, and 8.2%, which are comparable to that of the benchmark YD2-o-C8 (eta = 8.25%) under similar conditions. It was demonstrated that 2-carboxypyridine is an efficient and stable anchoring group as MH1 and showed better cell performance and long-term stability than YD2-o-C8 under light soaking conditions.


Published in:
Acs Applied Materials & Interfaces, 7, 27, 14975-14982
Year:
2015
Publisher:
Washington, Amer Chemical Soc
ISSN:
1944-8244
Keywords:
Laboratories:




 Record created 2015-09-28, last modified 2018-09-13


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