Syntheses, structures and properties of cobalt and manganese complexes based on pyridine-2,3,5,6-tetracarboxylic acid

Two new complexes based on pyridine-2,3,5,6-tetracarboxylic acid(H(4)pdtc) as ligand, {[Co-2(pdtc)(H2O)(4)]center dot H2O}(n) (1) and {Mn-2(pdtc)(H2O)(4)}(n) (2), have been obtained by hydrothermal syntheses and characterized by IR, elemental analysis, X-ray diffraction single crystal structure analysis, PXRD, thermal gravimetric analysis, and magnetic measurements. Complex 1 is 3D coordination polymer and complex 2 belongs to 2D grid structure by covalent bonds. In 1 and 2, the metal ions show antiferromagnetic interactions. (C) 2015 Elsevier B.V. All rights reserved.


Published in:
Inorganic Chemistry Communications, 58, 27-30
Year:
2015
Publisher:
Amsterdam, Elsevier Science Bv
ISSN:
1387-7003
Keywords:
Laboratories:




 Record created 2015-09-28, last modified 2018-09-13


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