Syntheses, structures and properties of cobalt and manganese complexes based on pyridine-2,3,5,6-tetracarboxylic acid
Gao, Hong-Ling; Bi, Yan-Xia; Li, Fang-Fang; Cheung, Chi Wai; Wang, Wen-Min; Shen, Hai-Yun; Cui, Jian-Zhong
2015

Abstract

Two new complexes based on pyridine-2,3,5,6-tetracarboxylic acid(H(4)pdtc) as ligand, {[Co-2(pdtc)(H2O)(4)]center dot H2O}(n) (1) and {Mn-2(pdtc)(H2O)(4)}(n) (2), have been obtained by hydrothermal syntheses and characterized by IR, elemental analysis, X-ray diffraction single crystal structure analysis, PXRD, thermal gravimetric analysis, and magnetic measurements. Complex 1 is 3D coordination polymer and complex 2 belongs to 2D grid structure by covalent bonds. In 1 and 2, the metal ions show antiferromagnetic interactions. (C) 2015 Elsevier B.V. All rights reserved.

Details

Title Syntheses, structures and properties of cobalt and manganese complexes based on pyridine-2,3,5,6-tetracarboxylic acid
Author(s) Gao, Hong-Ling ; Bi, Yan-Xia ; Li, Fang-Fang ; Cheung, Chi Wai ; Wang, Wen-Min ; Shen, Hai-Yun ; Cui, Jian-Zhong
Published in Inorganic Chemistry Communications
Pagination 4
Volume 58
Pages 27-30
Date 2015
Publisher Amsterdam, Elsevier Science Bv
ISSN 1387-7003
Keywords
DOI https://doi.org/10.1016/j.inoche.2015.05.001
Other identifier(s) View record in Web of Science
Laboratories LSCI
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LSCI - Laboratory of Inorganic Synthesis and Catalysis
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2015-09-28

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