Transforming terpene feedstock into polyketide architecture

The Cu-catalyzed synthesis of skipped 1,4-dienes from allylic acetates and vinyl-Grignard reagents is key to bidirectional modifications of acyclic terpene acetates. As a result, trisubstituted double bond containing subunits can be readily transferred into complex polyketides from inexpensive bulk terpenes.


Published in:
Chemical Communications- Royal Society of Chemistry, 47, 1, 394-396
Year:
2011
Publisher:
Royal Society of Chemistry
ISSN:
1359-7345
Laboratories:




 Record created 2015-09-01, last modified 2018-09-13

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