000208801 001__ 208801
000208801 005__ 20180913063137.0
000208801 0247_ $$2doi$$a10.1021/acsnano.5b02547
000208801 022__ $$a1936-086X
000208801 02470 $$2ISI$$a000356988500099
000208801 037__ $$aARTICLE
000208801 245__ $$aInterfacial Redox Catalysis on Gold Nanofilms at Soft Interfaces
000208801 260__ $$aWashington$$bAmer Chemical Soc$$c2015
000208801 269__ $$a2015
000208801 300__ $$a11
000208801 336__ $$aJournal Articles
000208801 520__ $$aSoft or “liquid-liquid” interfaces were functionalized by half a monolayer of mirror-like nanofilms of gold nanoparticles using a precise interfacial microinjection method. The surface coverage of the nanofilm was characterized by ion transfer voltammetry. These gold nanoparticle films represent an ideal model system for studying both the thermodynamic and kinetic aspects of interfacial redox catalysis. The electric polarization of these soft interfaces is easily controllable and thus the Fermi level of the electrons in the interfacial gold nanoparticle film can be easily manipulated. Here, we study interfacial redox catalysis between two redox couples located in adjacent immiscible phases and highlight the catalytic properties of a gold nanoparticle film towards heterogeneous electron transfer reactions.
000208801 6531_ $$agold nanoparticles
000208801 6531_ $$aFermi level equilibration
000208801 6531_ $$aliquid-liquid interfaces
000208801 6531_ $$aredox catalysis
000208801 6531_ $$aelectron transfer
000208801 6531_ $$ananofilm
000208801 700__ $$0246944$$aSmirnov, Evgeny$$g227763
000208801 700__ $$0247474$$aPeljo, Pekka$$g218461
000208801 700__ $$0245629$$aScanlon, Micheal D.$$g217888
000208801 700__ $$0242739$$aGirault, Hubert H.$$g105258
000208801 773__ $$j9$$k6$$q6565–6575$$tACS Nano
000208801 8564_ $$s4675301$$uhttps://infoscience.epfl.ch/record/208801/files/acsnano2E5b02547.pdf$$yPublisher's version$$zPublisher's version
000208801 8564_ $$s61900$$uhttps://infoscience.epfl.ch/record/208801/files/nn-2015-02547c_0009.gif$$yTOC figure$$zTOC figure
000208801 8564_ $$s1674115$$uhttps://infoscience.epfl.ch/record/208801/files/nn5b02547_si_001.pdf$$ySupporting Information$$zSupporting Information
000208801 8564_ $$s4488690$$uhttps://infoscience.epfl.ch/record/208801/files/nn5b02547_si_002.avi$$ySupporting Information Movie$$zSupporting Information Movie
000208801 909C0 $$0252090$$pLEPA$$xU10100
000208801 909CO $$ooai:infoscience.tind.io:208801$$pSB$$particle
000208801 917Z8 $$x208650
000208801 917Z8 $$x208650
000208801 937__ $$aEPFL-ARTICLE-208801
000208801 973__ $$aEPFL$$rREVIEWED$$sPUBLISHED
000208801 980__ $$aARTICLE