Insights into the Catalytic Activity of Nitridated Fibrous Silica (KCC-1) Nanocatalysts from N-15 and Si-29 NMR Spectroscopy Enhanced by Dynamic Nuclear Polarization

Fibrous nanosilica (KCC-1) oxynitrides are promising solid-base catalysts. Paradoxically, when their nitrogen content increases, their catalytic activity decreases. This counterintuitive observation is explained here for the first time using N-15-solid-state NMR spectroscopy enhanced by dynamic nuclear polarization.


Published in:
Angewandte Chemie-International Edition, 54, 7, 2190-2193
Year:
2015
Publisher:
Weinheim, Wiley-Blackwell
ISSN:
1433-7851
Keywords:
Laboratories:


  • n/a: P384a-Supp-Lilly-Thankamony-Lion-Pourpoint-Singh-Perez-Linde-Carnevale-Bodenhausen-Vezin-Lafon-Polshettiwar Angew-Chem-54-21980-2015 - PDF; P384-Lilly-Thankamony-Lion-Pourpoint-Singh-Perez-Linde-Carnevale-Bodenhausen-Vezin-Lafon-Polshettiwar Angew-Chem-54-21980-2015 - PDF;
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 Record created 2015-05-29, last modified 2018-03-17

n/a:
P384a-Supp-Lilly-Thankamony-Lion-Pourpoint-Singh-Perez-Linde-Carnevale-Bodenhausen-Vezin-Lafon-Polshettiwar Angew-Chem-54-21980-2015 - Download fulltextPDF
P384-Lilly-Thankamony-Lion-Pourpoint-Singh-Perez-Linde-Carnevale-Bodenhausen-Vezin-Lafon-Polshettiwar Angew-Chem-54-21980-2015 - Download fulltextPDF
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