000207617 001__ 207617
000207617 005__ 20180913063101.0
000207617 0247_ $$2doi$$a10.1016/j.cplett.2015.03.036
000207617 022__ $$a0009-2614
000207617 02470 $$2ISI$$a000353514300014
000207617 037__ $$aARTICLE
000207617 245__ $$aDissociation threshold of H218O: Validating ab initio calculations by state-selective triple-resonance spectroscopy
000207617 269__ $$a2015
000207617 260__ $$aAmsterdam$$bElsevier$$c2015
000207617 300__ $$a4
000207617 336__ $$aJournal Articles
000207617 520__ $$aWe employ state-selective triple-resonance vibrational overtone spectroscopy for a direct measurement of the lowest dissociation energy, Do, in the (H2O)-O-18 molecule. The measured value of 41 154.22 +/- 0.25 cm(-1) is in an excellent agreement with that, predicted by ab initio theoretical calculations. This result validates the computations, adding more confidence to what this theory can predict for water. In addition, we have measured the required for this experiment energy levels of (H2O)-O-18 in the region near 27 000 cm(-1), as well as the laser-induced fluorescence (LIF) spectrum of the (OH)-O-18 isotopologue, for which near 60 electronic transitions have been assigned. (C) 2015 Elsevier B.V. All rights reserved.
000207617 700__ $$aMakarov, D. S.
000207617 700__ $$aKoshelev, M. A.
000207617 700__ $$aZobov, N. F.
000207617 700__ $$0242817$$aBoyarkin, Oleg V.$$g104570
000207617 773__ $$j627$$q73-76$$tChemical Physics Letters
000207617 8564_ $$s484355$$uhttps://infoscience.epfl.ch/record/207617/files/1-s2.0-S0009261415001967-main.pdf$$yPublisher's version$$zPublisher's version
000207617 909C0 $$0252096$$pLCPM$$xU10106
000207617 909CO $$ooai:infoscience.tind.io:207617$$pSB$$particle
000207617 917Z8 $$x104570
000207617 937__ $$aEPFL-ARTICLE-207617
000207617 973__ $$aEPFL$$rREVIEWED$$sPUBLISHED
000207617 980__ $$aARTICLE