000207329 001__ 207329
000207329 005__ 20180913063054.0
000207329 0247_ $$2doi$$a10.1021/jp512013n
000207329 022__ $$a1932-7447
000207329 02470 $$2ISI$$a000350329300006
000207329 037__ $$aARTICLE
000207329 245__ $$aThe Role of Transport Agents in MoS2 Single Crystals
000207329 260__ $$aWashington$$bAmer Chemical Soc$$c2015
000207329 269__ $$a2015
000207329 300__ $$a5
000207329 336__ $$aJournal Articles
000207329 520__ $$aWe report resistivity, thermoelectric power, and thermal conductivity of MoS2 single crystals prepared by the chemical vapor transport (CVT) method using I-2, Br-2, and TeCl4 as transport agents. The material presents low-lying donor and acceptor levels, which dominate the in-plane charge transport. Intercalates into the van der Waals gap strongly influence the interplane resistivity. Thermoelectric power displays the characteristics of strong electron-phonon interaction. A detailed theoretical model of thermal conductivity reveals the presence of a high number of defects in the MoS2 structure. We show that these defects are inherent to CVT growth method, coming mostly from the transport agent molecules inclusion as identified by total reflection X-ray fluorescence analysis (TXRF) and in-beam activation analysis (IBAA).
000207329 700__ $$0246855$$aPisoni, Andrea$$g227410$$uEcole Polytech Fed Lausanne, Lab Phys Complex Matter, CH-1015 Lausanne, Switzerland
000207329 700__ $$0244813$$aJacimovic, Jacim$$g187212$$uEcole Polytech Fed Lausanne, Lab Phys Complex Matter, CH-1015 Lausanne, Switzerland
000207329 700__ $$aBarisic, Osor S.$$uInst Phys, HR-10000 Zagreb, Croatia
000207329 700__ $$aWalter, Arnaud$$uEcole Polytech Fed Lausanne, Lab Phys Complex Matter, CH-1015 Lausanne, Switzerland
000207329 700__ $$0240587$$aNafradi, Balint$$g167625$$uEcole Polytech Fed Lausanne, Lab Phys Complex Matter, CH-1015 Lausanne, Switzerland
000207329 700__ $$aBugnon, Phillipe$$uEcole Polytech Fed Lausanne, Single Crystal Growth Facil, CH-1015 Lausanne, Switzerland
000207329 700__ $$0240302$$aMagrez, Arnaud$$g161833$$uEcole Polytech Fed Lausanne, Single Crystal Growth Facil, CH-1015 Lausanne, Switzerland
000207329 700__ $$aBerger, Helmuth$$uEcole Polytech Fed Lausanne, Single Crystal Growth Facil, CH-1015 Lausanne, Switzerland
000207329 700__ $$aRevay, Zsolt
000207329 700__ $$0240227$$aForro, Laszlo$$g105148$$uEcole Polytech Fed Lausanne, Lab Phys Complex Matter, CH-1015 Lausanne, Switzerland
000207329 773__ $$j119$$k8$$q3918-3922$$tJournal Of Physical Chemistry C
000207329 909C0 $$0252321$$pLPMC$$xU10142
000207329 909CO $$ooai:infoscience.tind.io:207329$$pSB$$particle
000207329 937__ $$aEPFL-ARTICLE-207329
000207329 973__ $$aEPFL$$rREVIEWED$$sPUBLISHED
000207329 980__ $$aARTICLE