Sample restriction using radiofrequency field selective pulses in high-resolution solid-state NMR

In this article a method is suggested for restricting a sample (spatial localization) by preparing the magnetization with a phase-modulated radiofrequency pulse which inverts magnetization only over a very narrow range of radiofrequency field strengths. This is the most efficient method, in terms of sensitivity, of restricting the sample to improve rf homogeneity. The method is demonstrated by using it to improve the resolution obtained in a homonuclear dipolar decoupling experiment. (C) 2002 Elsevier Science.


Published in:
Journal of Magnetic Resonance, 154, 1, 136-141
Year:
2002
Publisher:
ACADEMIC PRESS INC ELSEVIER SCIENCE
ISSN:
1090-7807
Laboratories:




 Record created 2015-01-08, last modified 2018-09-13


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