research article
Synthesis and reactivity of molybdenum imido alkylidene bis-pyrazolide complexes
2010
Reaction of Li(3,5-R(2)-pyrazolide) (R = tBu or Ph, dXpz) with Mo(NAr)(CHCMe(2)Ph)(OTf)(2)(DME) yields Mo(NAr)(CHCMe(2)Ph)(dXpz)(2) in good yield. These complexes react with alcohols or the surface silanols of silica, to yield bis-alkoxy and surface mono-siloxy alkene metathesis catalysts, respectively.
Type
research article
Web of Science ID
WOS:000281605800024
Author(s)
Gajan, David
Rendon, Nuria
Wampler, Keith M.
Basset, Jean-Marie
Coperet, Christophe
Lesage, Anne
Schrock, Richard R.
Date Issued
2010
Publisher
Published in
Volume
39
Issue
36
Start page
8547
End page
8551
Editorial or Peer reviewed
REVIEWED
Written at
OTHER
EPFL units
Available on Infoscience
January 8, 2015
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