Synthesis and reactivity of molybdenum imido alkylidene bis-pyrazolide complexes
Gajan, David; Rendon, Nuria; Wampler, Keith M.; Basset, Jean-Marie; Coperet, Christophe; Lesage, Anne; Emsley, Lyndon; Schrock, Richard R.
2010

Abstract

Reaction of Li(3,5-R(2)-pyrazolide) (R = tBu or Ph, dXpz) with Mo(NAr)(CHCMe(2)Ph)(OTf)(2)(DME) yields Mo(NAr)(CHCMe(2)Ph)(dXpz)(2) in good yield. These complexes react with alcohols or the surface silanols of silica, to yield bis-alkoxy and surface mono-siloxy alkene metathesis catalysts, respectively.

Details

Title Synthesis and reactivity of molybdenum imido alkylidene bis-pyrazolide complexes
Author(s) Gajan, David ; Rendon, Nuria ; Wampler, Keith M. ; Basset, Jean-Marie ; Coperet, Christophe ; Lesage, Anne ; Emsley, Lyndon ; Schrock, Richard R.
Published in Dalton Transactions
Volume 39
Issue 36
Pages 8547-8551
Date 2010
Publisher ROYAL SOC CHEMISTRY
ISSN 1477-9226
DOI https://doi.org/10.1039/c0dt00315h
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Laboratories LRM
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LRM - Laboratory of Magnetic Resonance
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date 2015-01-08