Probing surface site heterogeneity through 1D and INADEQUATE P-31 solid state NMR spectroscopy of silica supported PMe3-Au(I) adducts
2011
Abstract
Grafting of (Me3Si)(2)N-AuPMe3 on SiO2-(700) leads to the formation of [( SiO)Au-PMe3] located in different surface environments due to the presence or absence of adjacent siloxane bridges, as shown both by P-31 solid state NMR and by its conversion into a mixture of [( SiO)Au-PMe3] and [( SiO)Au(PMe3)(2)] upon exposure to PMe3.
Details
Title
Probing surface site heterogeneity through 1D and INADEQUATE P-31 solid state NMR spectroscopy of silica supported PMe3-Au(I) adducts
Author(s)
Gajan, David ; Levine, Daniel ; Zocher, Eva ; Coperet, Christophe ; Lesage, Anne ; Emsley, Lyndon
Published in
CHEMICAL SCIENCE
Volume
2
Issue
5
Pages
928-931
Date
2011
Publisher
ROYAL SOC CHEMISTRY
ISSN
2041-6520
Other identifier(s)
View record in Web of Science
Laboratories
LRM
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LRM - Laboratory of Magnetic Resonance
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date
2015-01-08