High-resolution and sensitivity through-bond correlations in ultra-fast magic angle spinning (MAS) solid-state NMR

We introduce a new experiment, which makes use of Spin State Selective manipulations to perform sensitive and resolved through-bond correlations in organic and biological solids at high-fields and under ultra-fast MAS. The scheme is the shortest and most sensitive through-bond correlation method introduced so far in solids, yields resolved fingerprints of uniformly (13)C-labeled biomolecules, and constitutes a tool to highlight slight static structural disorder around crystallographically equivalent molecules in microcrystalline samples.


Published in:
CHEMICAL SCIENCE, 2, 2, 345-348
Year:
2011
Publisher:
ROYAL SOC CHEMISTRY
ISSN:
2041-6520
Laboratories:




 Record created 2015-01-08, last modified 2018-03-17


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