Molecular-level characterization of the structure and the surface chemistry of periodic mesoporous organosilicates using DNP-surface enhanced NMR spectroscopy
Gruening, Wolfram R.; Rossini, Aaron J.; Zagdoun, Alexandre; Gajan, David; Lesage, Anne; Emsley, Lyndon; Coperet, Christophe
2013

Abstract

We present the molecular level characterization of a phenylpyridine-based periodicmesoporous organosilicate and its post-functionalized organometallic derivatives through the fast acquisition of high quality natural isotopic abundance 1D C-13, N-15, and Si-29 and 2D 1H-C-13 and 1H-Si-29 solid-state NMR spectra enhanced with dynamic nuclear polarization.

Details

Title Molecular-level characterization of the structure and the surface chemistry of periodic mesoporous organosilicates using DNP-surface enhanced NMR spectroscopy
Author(s) Gruening, Wolfram R. ; Rossini, Aaron J. ; Zagdoun, Alexandre ; Gajan, David ; Lesage, Anne ; Emsley, Lyndon ; Coperet, Christophe
Published in Physical Chemistry Chemical Physics
Volume 15
Issue 32
Pages 13270-13274
Date 2013
Publisher ROYAL SOC CHEMISTRY
ISSN 1463-9076
DOI https://doi.org/10.1039/c3cp00026e
Other identifier(s) View record in Web of Science
Laboratories LRM
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LRM - Laboratory of Magnetic Resonance
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date 2015-01-08

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