Molecular-level characterization of the structure and the surface chemistry of periodic mesoporous organosilicates using DNP-surface enhanced NMR spectroscopy
2013
Abstract
We present the molecular level characterization of a phenylpyridine-based periodicmesoporous organosilicate and its post-functionalized organometallic derivatives through the fast acquisition of high quality natural isotopic abundance 1D C-13, N-15, and Si-29 and 2D 1H-C-13 and 1H-Si-29 solid-state NMR spectra enhanced with dynamic nuclear polarization.
Details
Title
Molecular-level characterization of the structure and the surface chemistry of periodic mesoporous organosilicates using DNP-surface enhanced NMR spectroscopy
Author(s)
Gruening, Wolfram R. ; Rossini, Aaron J. ; Zagdoun, Alexandre ; Gajan, David ; Lesage, Anne ; Emsley, Lyndon ; Coperet, Christophe
Published in
Physical Chemistry Chemical Physics
Volume
15
Issue
32
Pages
13270-13274
Date
2013
Publisher
ROYAL SOC CHEMISTRY
ISSN
1463-9076
Other identifier(s)
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Laboratories
LRM
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LRM - Laboratory of Magnetic Resonance
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date
2015-01-08