Well-defined mono(eta(3)-allyl)nickel complex MONi(eta(3)-C3H5) (M = Si or Al) grafted onto silica or alumina: a molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticles
Li, Lidong; Abou-Hamad, Edy; Anjum, Dalaver H.; Zhou, Lu; Laveille, Paco V.; Emsley, Lyndon; Basset, Jean-Marie
2014

Abstract

Preparing evenly-dispersed small size nickel nanoparticles over inert oxides remains a challenge today. In this context, a versatile method to prepare supported small size nickel nanoparticles (ca. 1-3 nm) with narrow size distribution via a surface organometallic chemistry (SOMC) route is described. The grafted mono(eta(3)-allyl) nickel complexes RMONi(eta(3)-C3H5) (M = Si or Al) as precursors are synthesized and fully characterized by elemental analysis, FTIR spectroscopy and paramagnetic solid-state NMR.

Details

Title Well-defined mono(eta(3)-allyl)nickel complex MONi(eta(3)-C3H5) (M = Si or Al) grafted onto silica or alumina: a molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticles
Author(s) Li, Lidong ; Abou-Hamad, Edy ; Anjum, Dalaver H. ; Zhou, Lu ; Laveille, Paco V. ; Emsley, Lyndon ; Basset, Jean-Marie
Published in Chemical Communications
Volume 50
Issue 57
Pages 7716-7719
Date 2014
Publisher ROYAL SOC CHEMISTRY
ISSN 1359-7345
DOI https://doi.org/10.1039/c4cc02962c
Other identifier(s) View record in Web of Science
Laboratories LRM
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LRM - Laboratory of Magnetic Resonance
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date 2015-01-08

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