Cross polarization from H-1 to quadrupolar Li-6 nuclei for dissolution DNP
Linde, Angel J. Perez; Bornet, Aurelien; Milani, Jonas; Vuichoud, Basile; Melzi, Roberto; Jannin, Sami; Bodenhausen, Geoffrey
2014

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Abstract

Cross polarization from protons to quadrupolar Li-6 nuclei is combined with dynamic nuclear polarization of protons at 1.2 K and 6.7 T using TEMPOL as a polarizing agent followed by rapid dissolution. Compared to direct Li-6 DNP without cross-polarization, a higher nuclear spin polarization P(Li-6) can be obtained in a shorter time. A double resonance H-1-Li-6 probe was designed that is equipped for Longitudinally Detected Electron Spin Resonance.

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Title Cross polarization from H-1 to quadrupolar Li-6 nuclei for dissolution DNP
Author(s) Linde, Angel J. Perez ; Bornet, Aurelien ; Milani, Jonas ; Vuichoud, Basile ; Melzi, Roberto ; Jannin, Sami ; Bodenhausen, Geoffrey
Published in Physical Chemistry Chemical Physics
Pagination 5
Volume 16
Issue 45
Pages 24813-24817
Date 2014
Publisher Cambridge, Royal Society of Chemistry
ISSN 1463-9076
DOI https://doi.org/10.1039/c4cp03592e
Other identifier(s) View record in Web of Science
Laboratories LRMB
Record Appears in Scientific production and competences > SB - School of Basic Sciences > SB Archives > LRMB - Laboratory of Biomolecular Magnetic Resonance
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2014-12-30

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