Room temperature alkynylation of H-phosphi(na)tes and secondary phosphine oxides with ethynylbenziodoxolone (EBX) reagents
Chen, C. Chun; Waser, Jerome
2014

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Abstract

Highly efficient protocols for the alkynylation of H-phosphi(na)tes and secondary phosphine oxides with silyl, aryl and alkyl ethynyl-benziodoxolone (EBX) reagents are reported. Alkynyl phosphorus compounds were obtained in 69-93% yield without the need for a transition metal catalyst at room temperature under open flask conditions.

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Title Room temperature alkynylation of H-phosphi(na)tes and secondary phosphine oxides with ethynylbenziodoxolone (EBX) reagents
Author(s) Chen, C. Chun ; Waser, Jerome
Published in Chemical Communications
Pagination 4
Volume 50
Issue 85
Pages 12923-12926
Date 2014
Publisher Cambridge, Royal Society of Chemistry
ISSN 1359-7345
Keywords
DOI https://doi.org/10.1039/c4cc06851c
Other identifier(s) View record in Web of Science
Laboratories LCSO
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCSO - Laboratory of Catalysis and Organic Synthesis
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2014-11-13

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