Ligand assisted cleavage of uranium oxo-clusters
Nocton, Gregory; Pecaut, Jacques; Filinchuk, Yaroslav; Mazzanti, Marinella
2010

Abstract

Dibenzoylmethanate replaces the bridging triflate ligands in uranium triflate polyoxo-clusters and cleaves the U12O20 core yielding the new [U6O4(OH)4(η-dbm) 12] dibenzoylmethanate (dbm-) cluster which slowly dissociates into a monomeric complex. This reactivity demonstrates the importance of bridging ligands in stabilizing uranium polyoxo-clusters. © 2010 The Royal Society of Chemistry.

Details

Title Ligand assisted cleavage of uranium oxo-clusters
Author(s) Nocton, Gregory ; Pecaut, Jacques ; Filinchuk, Yaroslav ; Mazzanti, Marinella
Published in Chemical Communications
Volume 46
Issue 16
Pages 2757-2759
Date 2010
ISSN 1359-7345
DOI https://doi.org/10.1039/b926580e
Other identifier(s) View record in Web of Science
Laboratories GCC
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > GCC - Group of Coordination Chemistry
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date 2014-11-07

Actions