U(iv) promotes the disproportionation of otherwise stable uranyl(v) Schiff base complexes affording U(iv)-U(v) oxo clusters with new geometries and the first example of a U(iv)⋯UO 2 + cation-cation interaction.
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Title
New polynuclear U(IV)-U(V) complexes from U(IV) mediated uranyl(V) disproportionation