Siloxides as Supporting Ligands in Uranium(III)-Mediated Small-Molecule Activation
Mougel, Victor; Camp, Clement; Pecaut, Jacques; Coperet, Christophe; Maron, Laurent; Kefalidis, Christos E.; Mazzanti, Marinella
2012

Abstract

Siloxides can support U! in the reduction of small molecules with uranium complexes. The treatment of [UN(SiMe3)23] with HOSi(OtBu)3 (3 equiv) yielded a novel homoleptic uranium(III) siloxide complex 1, which acted as a two-electron reducing agent toward CS 2 and CO2 (see scheme). Complex 1 also reduced toluene to afford a diuranium inverted-sandwich complex. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Details

Title Siloxides as Supporting Ligands in Uranium(III)-Mediated Small-Molecule Activation
Author(s) Mougel, Victor ; Camp, Clement ; Pecaut, Jacques ; Coperet, Christophe ; Maron, Laurent ; Kefalidis, Christos E. ; Mazzanti, Marinella
Published in Angewandte Chemie-International Edition
Volume 51
Issue 49
Pages 12280-12284
Date 2012
ISSN 1433-7851
DOI https://doi.org/10.1002/anie.201206955
Other identifier(s) View record in Web of Science
Laboratories GCC
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > GCC - Group of Coordination Chemistry
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date 2014-11-07

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