Single-ion magnet behaviour in U(Tp(Me2))(2)I
2012
Abstract
[U(TpMe2)2I] exhibits at low temperatures single molecule magnet (SMM) behaviour comparable to its bipyridine derivative and related single ion U(iii) complexes recently reported as SMMs. The trend of variation of the energy barrier for the magnetic relaxation in these compounds is well reproduced by quantum chemistry calculations. © The Royal Society of Chemistry 2012.
Details
Title
Single-ion magnet behaviour in U(Tp(Me2))(2)I
Author(s)
Coutinho, Joana T. ; Antunes, Maria A. ; Pereira, Laura C. J. ; Bolvin, Helene ; Marcalo, Joaquim ; Mazzanti, Marinella ; Almeida, Manuel
Published in
Dalton Transactions
Volume
41
Issue
44
Pages
13568-13571
Date
2012
ISSN
1477-9226
Other identifier(s)
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Laboratories
GCC
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > GCC - Group of Coordination Chemistry
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date
2014-11-07