Multielectron Redox Reactions Involving C-C Coupling and Cleavage in Uranium Schiff Base Complexes
2010
Abstract
The reaction of U(III) with Schiff base ligands and the reduction of U(IV) Schiff base complexes both promote C-C bond formation to afford dinuclear or mononuclear U(IV) amido complexes, which can release up to four electrons to substrates through the oxidative cleavage of the C-C bond. © 2010 American Chemical Society.
Details
Title
Multielectron Redox Reactions Involving C-C Coupling and Cleavage in Uranium Schiff Base Complexes
Author(s)
Camp, Clement ; Mougel, Victor ; Horeglad, Pawel ; Pecaut, Jacques ; Mazzanti, Marinella
Published in
Journal of the American Chemical Society
Volume
132
Issue
49
Pages
17374-17377
Date
2010
ISSN
0002-7863
Other identifier(s)
View record in Web of Science
Laboratories
GCC
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > GCC - Group of Coordination Chemistry
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date
2014-11-07