000202989 001__ 202989
000202989 005__ 20180913062819.0
000202989 0247_ $$2doi$$a10.1002/anie.201307291
000202989 022__ $$a1433-7851
000202989 02470 $$2ISI$$a000327582900032
000202989 037__ $$aARTICLE
000202989 245__ $$aControlled Thermolysis of Uranium (Alkoxy) siloxy Complexes: A Route to Polymetallic Complexes of Low-Valent Uranium
000202989 260__ $$c2013
000202989 269__ $$a2013
000202989 336__ $$aJournal Articles
000202989 520__ $$aDecomposition into higher species: Intramolecular UIII-mediated homolytic C-O bond cleavage in UIII (alkoxy)siloxy complexes at low temperature and subsequent reduction with KC8 led to unprecedented polymetallic complexes containing siloxy, silanediolate, and silanetriolate ligands (see example: U green, Si yellow, K blue, O red). Such compounds may be useful precursors to uranium ceramics relevant for catalysis and the storage of spent nuclear fuel. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
000202989 700__ $$aCamp, Clement
000202989 700__ $$aKefalidis, Christos E.
000202989 700__ $$aPecaut, Jacques
000202989 700__ $$aMaron, Laurent
000202989 700__ $$0248440$$aMazzanti, Marinella$$g166619
000202989 773__ $$j52$$k48$$q12646-12650$$tAngewandte Chemie-International Edition
000202989 909C0 $$0252515$$pGCC$$xU12966
000202989 909CO $$ooai:infoscience.tind.io:202989$$pSB$$particle
000202989 917Z8 $$x249835
000202989 937__ $$aEPFL-ARTICLE-202989
000202989 973__ $$aOTHER$$rREVIEWED$$sPUBLISHED
000202989 980__ $$aARTICLE